Faculty
Dr. Xin-Yuan xingkong星空中国官网 received his Bachelor degree from the department of chemistry, Anhui Normal University in 2001 and a Master degree in 2004 from Anhui Normal University in Cooperation with Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, China. Then, he became a Ph.D. candidate in Department of Chemistry, the University of Hong Kong under the supervision of Prof. Chi-Ming Che, and has been awarded a Ph.D. degree in 2010. He then successfully applied a Post-doctoral Fellow position in the University of Hong Kong and continued to work in the laboratory of Prof. Che. In 2011, he joined in the group of Prof. Carlos F. Barbas III at the Scripps Research Institute for a postdoc position. In September of 2012, Dr. xingkong星空中国官网 joined in the Department of Chemistry, SUSTech, and has set up an independent organic chemistry’s research group.His research interests are focused on transition-metal and organocatalyst-catalyzed organic chemistry, homogeneous and heterogeneous catalysis, organofluorine chemistry, and the application of chemistry in biological and medicinal chemistry. He has published more than forty research papers in international journals, including Angewandte Chemie International Edition, Chemical Communications, Organic Letters, Chemistry – A European Journal, ACS Catalysis. Citation times for his research papers have been up to 1300. Dr. xingkong星空中国官网 has been awarded Award for Outstanding Research Postgraduate Student for 2009-2010 in The University of Hong Kong (2011), and so on.
Research interests：
◆ Catalytic functionalization of unactivated alkenes and alkynes
◆ Asymmetric radical chemistry
◆ Design and application of homogenous and heterogeneous catalysis
◆ Organofluorine chemistry.
Educational background
◆ Ph.D., in Organic Chemistry, The University of Hong Kong, 2010;
◆ M.S., in Organic Chemistry, Anhui Normal University in Cooperation with Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 2004;
◆ B.S., in Chemistry, Anhui Normal University, 2001.
Professional experience
◆ 2012.9, Associate Professor, South University of Science and Technology of China;
◆ 2011-2012, Research Associate, the Scripps Research Institute, USA;
◆ 2010-2011, Post-doctoral Fellow, The University of Hong Kong;
◆ 2004-2005, Research Assistant, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.
Honors & Awards
◆ 2011，Award for Outstanding Research Postgraduate Student for 2009-2010 in The University of Hong Kong
◆ 2013，Peacock Plan Awardee, Shenzhen
Publications
93. Fu-xingkong星空中国官网 Wang+, Chang-Jiang Yang+, Ji-Ren Liu+, Ning-Yuan Yang, Xiao-Yang Dong , Ruo-Qi Jiang, Xiao-Yong Chang , Zhong-Liang xingkong星空中国官网, Guo-Xiong Xu, Dai-Lei Yuan, Yu-Shuai Zhang, Qiang-Shuai Gu,* Xin Hong,* and Xin-Yuan Liu* "Mechanism-based ligand design for copper-catalysed enantioconvergent C(sp3)–C(sp) cross-coupling of tertiary electrophiles with alkynes" Nat. Chem. 2022, 14, 949.
92. Xian-Yan Cheng+, Yu-Feng Zhang+*, Jia-Huan Wang, Qiang-Shuai Gu, Zhong-Liang xingkong星空中国官网*, and Xin-Yuan Liu* "A Counterion/Ligand-Tuned Chemo- and Enantioselective Copper-Catalyzed Intermolecular Radical 1,2-Carboamination of Alkenes." J. Am. Chem. Soc. 2022, 144, 18081.
91. Xiao-Yang Dong, Zhong-Liang xingkong星空中国官网, Qiang-Shuai Gu, and Xin-Yuan Liu* "Ligand Development for Copper-Catalyzed Enantioconvergent Radical Cross-Coupling of Racemic Alkyl Halides." J. Am. Chem. Soc. 2022, 144, 17319.
90. Peng-Fei Wang+, Jiao Yu+, Kai-Xin Guo+, Sheng-Peng Jiang, Ji-Jun Chen, Qiang-Shuai Gu, Ji-Ren Liu, Xin Hong, Zhong-Liang xingkong星空中国官网,* and Xin-Yuan Liu* "Design of Hemilabile N,N,N-Ligands in Copper-Catalyzed Enantioconvergent Radical Cross-Coupling of Benzyl/Propargyl Halides with Alkenylboronate Esters." J. Am. Chem. Soc. 2022, 144, 6442.
89. Fu-xingkong星空中国官网 Wang+, Lin Liu+, Chang-Jiang Yang, Cheng Luan, Yang Jing, Ji-Jun Chen, Qiang-Shuai Gu, Zhong-Liang xingkong星空中国官网*, and Xin-Yuan Liu* "Synthesis of α-Quaternary β-Lactams via Copper-Catalyzed Enantioconvergent Radical C(sp3)–C(sp2) Cross-Coupling with Organoboronate Esters." Angew. Chem. Int. Ed. 2022, 61, e202214709.
88. Wu Yang+, Lin Liu+, Jiandong Guo+, Shou-Guo Wang, Jia-Yong Zhang, xingkong星空中国官网-Wen Fan, Yu Tian, xingkong星空中国官网-Lei Wang, Cheng Luan, Zhong-Liang xingkong星空中国官网, Chuan He, Xiaotai Wang*, Qiang-Shuai Gu*, Xin-Yuan Liu* "Enantioselective Hydroxylation of Dihydrosilanes to Si-Chiral Silanols Catalyzed by In Situ Generated Copper(II) Species." Angew. Chem. Int. Ed. 2022, 61, e202205743.
87. Feng-Ling Qing,* Xin-Yuan xingkong星空中国官网,* Jun-An Ma,* Qilong Shen,* Qiuling Song,* Pingping Tang* "A Fruitful Decadeof Organofluorine Chemistry: New Reagents and Reactions." CCS Chem. 2022, 4, 2518.
86. Cheng Luan+, Chang-Jiang Yang+, Lin xingkong星空中国官网, Qiang-Shuai Gu*, and Xin-Yuan xingkong星空中国官网* "Transition metal-catalyzed enantioselective C–P coupling reactions for the construction of P-stereogenic centers." Chem Catal. 2022, 2, 2876.
85. Na Wang, xingkong星空中国官网-Wen Fan, Jin Zhang, Qiang-Shuai Gu, Jin-Shun Lin, Guo-Qiang Chen,* Xin-Yuan Liu,* and Peiyuan Yu* "Chiral N-triflylphosphoramide-catalyzed asymmetric hydroamination of unactivated alkenes: a hetero-ene reaction mechanism." Org. Chem. Front. 2022, 9, 1649.
84. Jun-Bin Tang, Jun-Qian Bian, Yu-Shuai Zhang, Yong-Feng Cheng, Han-Tao Wen, Zhang-Long Yu, Zhong-Liang xingkong星空中国官网, Qiang-Shuai Gu,* Guo-Qiang Chen,* and Xin-Yuan Liu* "Copper-Catalyzed anti-Selective Radical 1,2-Alkylarylation of Terminal Alkynes." Org. Lett. 2022, 24, 2536.
83. Lin Liu, Kai-Xin Guo, Yu Tian, Chang-Jiang Yang, Qiang-Shuai Gu, Zhong-Liang xingkong星空中国官网, Liu Ye*, and Xin–Yuan Liu* "Copper-Catalyzed Intermolecular Enantioselective Radical Oxidative C(sp3)-H/C(sp)-H Cross-Coupling with Rationally Designed Oxazoline-Derived N,N,P(O)-Ligand." Angew. Chem. Int. Ed. 2021, 60, 26710
82. Yu-Feng Zhang+, Xiao-Yang Dong+, Jiang-Tao Cheng+, Ning-Yuan Yang, Li-Lei Wang, Fu-Li Wang, Cheng Luan, Juan Liu, Zhong-Liang Li, Qiang-Shuai Gu, and Xin-Yuan Liu* "Enantioconvergent Cu-Catalyzed Radical C−N Coupling of Racemic Secondary Alkyl Halides to Access α Chiral Primary Amines" J. Am. Chem. Soc. 2021, 143, 15413.
81. Chi Zhang, Zhong-Liang xingkong星空中国官网, Qiang-Shuai Gu* & Xin-Yuan Liu* "Catalytic enantioselective C(sp3)–H functionalization involving radical intermediates." Nat. Commun. 2021, 12, 475.
80. Huan Zhou+, Zhong-Liang xingkong星空中国官网+, Qiang-Shuai Gu, and Xin-Yuan Liu* "Ligand-Enabled Copper(I)-Catalyzed Asymmetric Radical C(sp3)−C Cross-Coupling Reactions." ACS Catal. 2021, 11, 7978.
79. Jiao Yu, Ning-Yuan Yang, Jiang-Tao Cheng, Tian-Ya Zhan, Cheng Luan, Liu Ye, Qiang-Shuai Gu, Zhong-Liang xingkong星空中国官网,* Guo-Qiang Chen,* and Xin-Yuan Liu* "Copper-Catalyzed Radical 1,2-Carbotrifluoromethylselenolation of Alkenes under Ambient Conditions" Org. Lett. 2021, 23, 1945.
78. Zheng-Hua Zhang, He Wei, Zhong-Liang xingkong星空中国官网*, Xin-Yuan Liu* "Recent Advances in Radical-Involved Alkynylation of Unactivated C(sp3)–H Bonds by Hydrogen Atom Abstraction." Synlett 2021, 32, 362.
77. Xiao-Long Su+, Sheng-Peng Jiang+, Liu Ye , Guo-Xing Xu, Ji-Jun Chen, Qiang-Shuai Gu, Zhong-Liang xingkong星空中国官网* , Xin-Yuan Liu* "A general copper-catalyzed radical C(sp3)-C(sp2) cross-coupling to access 1,1-diarylalkanes under ambient conditions." Tetrahedron 2021, 89, 132152.
76. Zhuang Li+, Xian-Yan Cheng+, Ning-Yuan Yang, Ji-Jun Chen, Wen-Yue Tang, Jun-Qian Bian, Yong-Feng Cheng, Zhong-Liang Li, Qiang-Shuai Gu,* and Xin-Yuan Liu* "A Cobalt-Catalyzed Enantioconvergent Radical Negishi C(sp3)−C(sp2) Cross-Coupling with Chiral Multidentate N,N,P Ligand." Organometallics 2021, 40, 2215.
75. Ning-Yuan Yang, Zhong-Liang xingkong星空中国官网,* Xin-Yuan Liu* "Recent progress in 1,1-diborylalkanes-involved asymmetric synthesis." Journal of Molecular Science, 2021, 37, 1.
74. Huan Zhou, Xin-Yuan xingkong星空中国官网* "Photoinduced Copper-Catalyzed Asymmetric C—O Cross-Coupling" Chin. J. Org. Chem. 2021, 41, 4510.
73. Xiao-Yang Dong+, Tian-Ya Zhan+, Sheng-Peng Jiang, Xiao-Dong Liu, Liu Ye, Zhong-Liang xingkong星空中国官网, Qiang- Shuai Gu, and Xin-Yuan Liu* "Copper-Catalyzed Asymmetric Coupling of Allenyl Radicals with Terminal Alkynes to Access Tetrasubstituted Allenes." Angew. Chem. Int. Ed. 2021, 60, 2160.
72. Xiao-Long Su+, Liu Ye+, Ji-Jun Chen+, Xiao-Dong Liu+, Sheng-Peng Jiang, Fu-xingkong星空中国官网 Wang, Lin Liu, Chang-Jiang Yang, Xiao-Yong Chang, Zhong-Liang xingkong星空中国官网, Qiang-Shuai Gu, and Xin-Yuan Liu* "Copper-Catalyzed Enantioconvergent Cross-Coupling of Racemic Alkyl Bromides with Azole C(sp3)–H Bonds." Angew. Chem. Int. Ed. 2021, 60, 380.
71. Sheng-Peng Jiang, Xiao-Yang Dong, Qiang-Shuai Gu, Liu Ye, Zhong-Liang xingkong星空中国官网,* and Xin-Yuan Liu* "Copper-Catalyzed Enantioconvergent Radical Suzuki–Miyaura C(sp3)–C(sp2) Cross-Coupling." J. Am. Chem. Soc. 2020, 142, 19652.
70. Zhe Wang,+ Jiang-Tao Cheng,+ Zhichao Shi, Na Wang, Feng Zhan, Sheng-Peng Jiang, Jin-Shun Lin,* Yuyang Jiang,* Xin-Yuan xingkong星空中国官网* "Catalytic Asymmetric Intermolecular Radical Aminotrifluoromethylation of Alkenes with Hydrazines by Cu(I)/CPA Cooperative Catalysis." ChemCatChem 2020, 13, 185.
69. Hai-Dong Xia,+ Zhong-Liang xingkong星空中国官网,+ Qiang-Shuai Gu,+ Xiao-Yang Dong,+ Jia-Heng Fang, Xuan-Yi Du, xingkong星空中国官网-Lei Wang, and Xin-Yuan Liu* "Photoinduced Copper-Catalyzed Asymmetric Decarboxylative Alkynylation with Terminal Alkynes." Angew. Chem. Int. Ed. 2020, 59, 16926.
68. Chang-Jiang Yang+, Chi Zhang+, Qiang-Shuai Gu+ , Jia-Heng Fang, Xiao-Long Su, Liu Ye, Yan Sun, Yu Tian, Zhong-Liang xingkong星空中国官网 and Xin-Yuan Liu* "Cu-catalysed intramolecular radical enantioconvergent tertiary β-C(sp3)–H amination of racemic ketones." Nat. Catal. 2020, 3, 539 .
67. Yong-Feng Cheng+, Ji-Ren Liu+, Qiang-Shuai Gu+, Zhang-Long Yu+, Jian Wang, Zhong-Liang xingkong星空中国官网, Jun-Qian Bian, Han-Tao Wen, Xiao-Jing Wang, Xin Hong* & Xin-Yuan Liu* "Catalytic enantioselective desymmetrizing functionalization of alkyl radicals via Cu(I)/CPA cooperative catalysis. " Nat. Catal. 2020, 3, 401.
66. Xiao-Yang Dong+, Jiang-Tao Cheng+, Yu-Feng Zhang+, Zhong-Liang xingkong星空中国官网+, Tian-Ya Zhan, Ji-Jun Chen, FuLi Wang, Ning-Yuan Yang, Liu Ye, Qiang-Shuai Gu, and Xin-Yuan Liu* ''Copper-Catalyzed Asymmetric Radical 1,2-Carboalkynylation of Alkenes with Alkyl Halides and Terminal Alkynes.'' J. Am. Chem. Soc. 2020, 142, 9501.
65. Xi-Tao xingkong星空中国官网+, Ling Lv+, Ting Wang+, Qiang-Shuai Gu, Guo-Xing Xu, Zhong-Liang xingkong星空中国官网, Liu Ye, Xinhao Zhang, Gui-Juan Cheng,* and Xin-Yuan Liu* ''Diastereo- and Enantioselective Catalytic Radical Oxysulfonylation of Alkenes in β,γ-Unsaturated Ketoximes.'' Chem 2020, 6, 1692.
64. Zhong-Liang xingkong星空中国官网,† Gui-Chun Fang,† Qiang-Shuai Gu † and Xin-Yuan Liu * ''Recent advances in copper-catalysed radical-involved asymmetric 1,2-difunctionalization of alkenes'' Chem. Soc. Rev. 2020, 49, 32.
63. Zhang-Long Yu+, Yong-Feng Cheng+, Na-Chuan Jiang, Jian Wang, xingkong星空中国官网-Wen Fan, Yue Yuan, Zhong-Liang xingkong星空中国官网, Qiang-Shuai Gu* and Xin-Yuan Liu* ''Desymmetrization of unactivated bis-alkenes via chiral Brønsted acid-catalysed hydroamination'' Chem. Sci. 2020, 11, 5987.
62. Yu-Xi Cao, Xiao-Yang Dong, Jun Yang, Sheng-Peng Jiang, Shuangliu Zhou, Zhong-Liang xingkong星空中国官网,* Guo-Qiang Chen,* and Xin-Yuan Liu* ”A Copper‐Catalyzed Sonogashira Coupling Reaction of Diverse Activated Alkyl Halides with Terminal Alkynes Under Ambient Conditions.” Adv. Synth. Catal. 2020, 362, 2280.
61. Zhen-Hua Zhang+, Xiao-Yang Dong+, Xuan-Yi Du+, Qiang-Shuai Gu , Zhong-Liang xingkong星空中国官网 & Xin-Yuan Liu* ''Copper-catalyzed enantioselective Sonogashira-type oxidative cross-coupling of unactivated C(sp3)−H bonds with alkyne.'' Nat. Commun. 2019, 10, 5689.
60. Liu Ye+, xingkong星空中国官网 Tian+, Xiang Meng, Qiang-Shuai Gu and Xin-Yuan Liu* ''Cu(I)/Chiral Phosphoric Acid-Catalyzed Radical-Involved Enantioselective Intramolecular Amination of Allylic and Benzylic C–H Bonds.'' Angew. Chem. Int. Ed. 2020, 59, 1129.
59. Xiao-Yang Dong+, Yu-Feng Zhang+, Can-Liang Ma+, Qiang-Shuai Gu+, Fu-xingkong星空中国官网 Wang+, Zhong-Liang xingkong星空中国官网, Sheng-Peng Jiang and Xin-Yuan Liu* "A general asymmetric copper-catalysed Sonogashira C(sp3)–C(sp) coupling" Nat. Chem. 2019, 11, 1158.
58. Qiang-Shuai Gu, Zhong-Liang xingkong星空中国官网, and Xin-Yuan Liu* "Copper(I)-Catalyzed Asymmetric Reactions Involving Radicals." Acc. Chem. Res. 2020, 53, 170.
57. Jin-Shun Lin, Tao-Tao xingkong星空中国官网, Ji-Ren Liu, Guan-Yuan Jiao, Qiang-Shuai Gu, Jiang-Tao Cheng, Yu-Long Guo, Xin Hong*, and Xin-Yuan Liu* "Cu/Chiral Phosphoric Acid-Catalyzed Asymmetric Three-Component Radical-Initiated 1,2-Dicarbofunctionalization of Alkenes." J. Am. Chem. Soc. 2019, 141, 1074.
56. Jin-Shun Lin, Tao-Tao xingkong星空中国官网, Guan-Yuan Jiao, Qiang-Shuai Gu, Jiang-Tao Cheng, Ling Lv, and Xin-Yuan Liu*, "Chiral Brønsted Acid‐Catalyzed Dynamic Kinetic Asymmetric Hydroamination of Racemic Allenes and Asymmetric Hydroamination of Dienes." Angew. Chem. Int. Ed. 2019, 58, 7092.
55. Yang Zeng, Xiao-Dong Liu, Xian-Qi Guo, Qiang-Shuai Gu*, Zhong-Liang xingkong星空中国官网*, Xiao-Yong Chang & Xin-Yuan Liu* "Cu/Chiral Phosphoric Acid-Catalyzed Radical-Initiated Asymmetric Aminosilylation of Alkene with Hydrosilane" Sci. China Chem. 2019, 62, 1529.
54. Gui Chun Fang, Yong Feng Cheng, Zhang Long Yu, Zhong Liang Li, Xin Yuan Liu，"Recent Advances in First Row Transition Metal/Chiral Phosphoric Acid Combined Catalysis." Top. Curr. Chem. 2019, 377, 23.
53. Na Wang, Qiang-Shuai Gu, Zhong-Liang xingkong星空中国官网, Zhuang xingkong星空中国官网, Yu-Long Guo, Zhen Guo, and Xin-Yuan Liu*, "Direct Photocatalytic Synthesis of Medium-Sized Lactams through C–C Bond Cleavage." Angew. Chem. Int. Ed. 2018, 57, 14225.
52. Xi-Tao xingkong星空中国官网, Qiang-Shuai Gu, Xiao-Yang Dong, Xiang Meng, and Xin-Yuan Liu*, "Cinchona Alkaloid‐Based Sulfonamide/Copper Catalyst for Asymmetric Radical Oxytrifluoromethylation of Alkenyl Oximes." Angew. Chem. Int. Ed. 2018, 57, 7668.
51. xingkong星空中国官网 Ye, Qiang-Shuai Gu, Guo-Cong Chen, and Xin-Yuan xingkong星空中国官网,* "Construction of Bicyclo[3.1.0]hexanes Containing Vicinal All-Carbon Quaternary Stereocenters via Radical Asymmetric Intramolecular α-Cyclopropanation of Aldehydes." Nat. Commun. 2018, 9, 227.
50. Jin-Hao Zhao, Yong Yang, Jin-Xin Che, Jun Zuo, Xiao-Hua xingkong星空中国官网, Yong-Zhou Hu, Xiao-Wu Dong,* Liang Gao,* and Xin-Yuan Liu*, “Compartmentalization of Incompatible Polymers within Metal–Organic Frameworks towards Homogenization of Heterogeneous Hybrid Catalysts for Tandem Reactions.” Chem. Eur. J. 2018, 24, 9903.
49. Na Wang, Jian Wang, Yu-Long Guo, Lei xingkong星空中国官网, Yan Sun, Zhuang xingkong星空中国官网, Hong-Xia Zhang, Zhen Guo, Zhong-Liang xingkong星空中国官网* and Xin-Yuan Liu *, “Oximinotrifluoromethylation of unactivated alkenes under ambient conditions.” Chem. Commun. 2018, 54, 8885.
48. Na Wang, Liu Ye, Zhong-Liang xingkong星空中国官网, Lei xingkong星空中国官网, Zhuang xingkong星空中国官网, Hong-Xia Zhang, Zhen Guo, QiangShuai Gu* and Xin-Yuan Liu*, “Hydrofunctionalization of Alkenols Triggered by Addition of Diverse Radicals to Unactivated Alkenes and Subsequent Remote Hydrogen Atom Translocation.” Org. Chem. Front. 2018, 5, 2810.
47. Xiao-Wu Dong*, Yong Yang, Jin-Xin Che, Jun Zuo, Xiao-Hua xingkong星空中国官网, Liang Gao, Yong-Zhou Hu and Xin-Yuan Liu*, “Heterogenization of homogeneous chiral polymers in metal–organic frameworks with enhanced catalytic performance for asymmetric catalysis.” Green Chem. 2018, 20, 4085.
46. Xi-Tao xingkong星空中国官网, Ling Lv, Qiang-Shuai Gu,*, and Xin-Yuan Liu*, “Copper-catalyzed radical oxytrifluoromethylation of alkenyl oximes at ambient temperature.” Tetrahedron, 2018, 74, 6041.
45. xingkong星空中国官网 Tian, Su Chen, Qiang-Shuai Gu, Jin-Shun Lin, Xin-Yuan Liu*, “Amino- and azidotrifluoromehtylation of alkenes.” Tetrahedron Lett. 2018, 59, 203. (Invited Digest)
44. Na Wang, Qiang-Shuai Gu*, Yong-Feng Cheng, Lei xingkong星空中国官网, Zhong-Liang xingkong星空中国官网, Zhen Guo*, and Xin-Yuan Liu*, “Visible-Light Promoted Preparation of Trifluoromethylated Tetrahydrofuran and Tetrahydropyran.” Chin. J. Org. Chem. 2019, 39, 200.
43. Xue-Fei xingkong星空中国官网, Jin-Shun Lin, Jian Wang, Zhong-Liang xingkong星空中国官网, Qiang-Shuai Gu, and Xin-Yuan Liu*, “Cu/Chiral Phosphoric Acid-Catalyzed Asymmetric Radical- Initiated Aminoarylation of Alkenes.” Acta Chim. Sinica 2018, 76, 878.
42. Fu-xingkong星空中国官网 Wang, Xiao-Yang Dong, Jin-Shun Lin, Yang Zeng, Guan-Yuan Jiao, Qiang-Shuai Gu, Xian-Qi Guo, and Xin-Yuan Liu*, “Catalytic Asymmetric Diamination of Unactivated Alkene with Dialkylaminyl Radical” Chem 2017, 3, 979.
41. Lei xingkong星空中国官网, Zhong-Liang xingkong星空中国官网, Qiang-Shuai Gu, Na Wang, Xin-Yuan Liu,* "A Remote Radical Vinyl Migration Strategy to Access Medium- and Large-sized Cyclic Alkenes" Sci. Adv. 2017, 3, e1701487.
40. Lei xingkong星空中国官网, Liu Ye, Shao-Fei Ni, Zhong-Liang xingkong星空中国官网, Su Chen, Yi-Meng Du, Xiao-Hua xingkong星空中国官网, xingkong星空中国官网 Dang* and Xin-Yuan Liu,* "Phosphine-catalyzed remote α-C–H bond activation of alcohols or amines triggered by the radical trifluoromethylation of alkenes: reaction development and mechanistic insights" Org. Chem. Front. 2017, 4, 2139.
39. Xue-Fei xingkong星空中国官网, Jin-Shun Lin and Xin-Yuan Liu,* “Catalytic Radical Intramolecular Aminoperfluoroalkylation and Aminodifluoromethylation of Unactivated Alkenes with Fluoroalkylsulfonyl Chlorides” Synthesis 2017, 49, 4213.
Published as part of the Special Topic Modern Cyclization Strategies in Synthesis
38. Jin-Shun Lin, Fu-xingkong星空中国官网 Wang, Xiao-Yang Dong, Wei-Wei He, Yue Yuan, Su Chen, and Xin-Yuan Liu,* "Catalytic Asymmetric Radical Aminoperfluoroalkylation and Aminodifluoromethylation of Alkenes: A Versatile Platform for Enantioenriched-Fluoroalkyl Amines" Nat. Commun. 2017, 8, 14841.
37. Yong-Feng Cheng, Xiao-Yang Dong, Qiang-Shuai Gu, Zhang-Long xingkong星空中国官网, and Xin-Yuan Liu* “Achiral Pyridine Ligand-Enabled Enantioselective Radical Oxytrifluoromethylation of Alkenes with Alcohols” Angew. Chem., Int. Ed. 2017, 56, 8883.
36 Taotao xingkong星空中国官网, Peng Yu, Yi-Meng Du, Jin-Shun Lin, Yonggang Zhi,* and Xin-Yuan Liu,* "Dual-Catalyzed Enantioselective Remote C−H Functionalization Triggered by Radical Trifluoromethylation of Alkenes: Highly Selective Formation of C−CF3 and C−C Bonds" J. Fluorine Chem. 2017, 203, 210. (invited paper for a special issue).
35 Lei xingkong星空中国官网, Qiang-Shuai Gu, Na Wang, Ping Song, Zhong-Liang xingkong星空中国官网, Xiao-Hua xingkong星空中国官网, Fu-xingkong星空中国官网 Wang, and Xin-Yuan Liu,* "1,2-Difunctionalization-Type (Hetero)arylation of Unactivated Alkenes Triggered by Radical Addition/Remote (Hetero)aryl Migration" Chem. Commun. 2017, 53, 4038.
34. Ping Song, Peng Yu, Jin-Shun Lin, Yiqun xingkong星空中国官网,* Ning-Yuan Yang, and Xin-Yuan Liu,* "Transition-Metal-Free β C−H Bond Carbonylation of Enamides or Amides with a Trifluoromethyl Group as CO Surrogate for the Synthesis of 1,3-Oxazin-6-ones" Org. Lett. 2017, 19, 1330.
33. Lei xingkong星空中国官网, Zhong-Liang xingkong星空中国官网, Fu-xingkong星空中国官网 Wang, Zhen Guo, Yong-Feng Cheng, Na Wang, Chao Fang, Jingjiang Liu, Chunhui Hou, Bin Tan, and Xin-Yuan Liu,* "Radical Aryl Migration Enables Diversity-Oriented Synthesis of Structurally Diverse Medium/Macro- or Bridged-Rings" Nat. Commun. 2016, 7, 13852.
32. Zhong-Liang xingkong星空中国官网, Xiao-Hua xingkong星空中国官网, Na Wang, Ning-Yuan Yang, and Xin-Yuan Liu,* "Radical-Mediated 1,2-Formyl/carbonyl-Functionalization of Alkenes and Application to Construction of Medium-Sized-, Fused-, and Bridged-Ring Systems" Angew. Chem., Int. Ed. 2016, 55, 15100.
31. Jin-Shun Lin, Xiao-Yang Dong, Tao-Tao xingkong星空中国官网, Na-Chuan Jiang, Bin Tan, and Xin-Yuan Liu,* "A Dual-Catalytic Strategy to Direct Asymmetric Radical Aminotrifluoromethylation of Alkenes" J. Am. Chem. Soc. 2016, 138, 9357.
30. Lin Huang, Liu Ye, Xiao-Hua xingkong星空中国官网, Zhong-Liang xingkong星空中国官网, Jin-Shun Lin, and Xin-Yuan Liu,* "Stereoselective Radical Cyclization Cascades Triggered by Addition of Diverse Radicals to Alkynes to Construct 6(5)‐6‐5 Fused Rings" Org. Lett., 2016, 18, 5284.
29. Na Wang, Lei xingkong星空中国官网, Zhong-Liang xingkong星空中国官网, Ning-Yuan Yang, Zhen Guo,* Hong-Xia Zhang, and Xin-Yuan Liu,* "Catalytic Diverse Radical-Mediated 1,2-Cyanofunctionalization of Unactivated Alkenes via Synergistic Remote Cyano Migration and Protected Strategies" Org. Lett., 2016, 18, 6026.
28. Ning-Yuan Yang, Zhong-Liang xingkong星空中国官网, Liu Ye, Bin Tan, and Xin-Yuan Liu,* "Organic base-catalysed solvent-tuned chemoselective carbotrifluoromethylation and oxytrifluoromethylation of unactivated alkenes" Chem. Commun., 2016, 52, 9052.
From themed collection 2016 Emerging Investigators by Chem. Commun.
27. Xiao-Long Yu, Liping Kuang, Su Chen, Xiao-Long Zhu, Zhong-Liang xingkong星空中国官网, Bin Tan, and Xin-Yuan Liu,* "Counteranion-Controlled Unprecedented Diastereo- and Enantioselective Tandem Povarov Reaction for Construction of Bioactive Octahydro-dipyrroloquinolines" ACS Catal. 2016, 6, 6182.
26. Na Wang, Sheng-Cai Zheng, Lin-Lin Zhang, Zhen Guo,* and Xin-Yuan xingkong星空中国官网* "Nickel(0)-Catalyzed Denitrogenative Transannulation of Triazoles with Alkynes: Mechanistic Insights of Chemical Reactivity, Regio- and Enantioselectivity from Density Functional Theory and Experiment" ACS Catal. 2016, 6, 3496.
25. Taotao xingkong星空中国官网, Peng Yu, Jin-Shun Lin, Yonggang Zhi,* and Xin-Yuan Liu,* "Copper-Catalyzed Redox-Triggered Remote C–H Functionalization: Highly Selective Formation of C–CF3 and C–O Bonds" Chin. J. Chem. 2016, 34, 490.
Invited paper for the Special Issue of “Trifluoromethylation and Trifluoromethythiolation Reactions”
24. Can-Liang Ma, Xiao-Hua xingkong星空中国官网, Xiao-Long Yu, Xiao-Long Zhu, Yong-Zhou Hu, Xiao-Wu Dong,* Bin Tan,* and Xin-Yuan Liu,* "Gold-catalyzed tandem synthesis of bioactive spiro-dipyrroloquinolines and its application in the one-step synthesis of incargranine B aglycone and seneciobipyrrolidine (I)" Org. Chem. Front. 2016, 3, 324.
From themed collection 2015 Emerging Investigators by OCF.
23. Zhi-Jia Fang, Sheng-Cai Zheng, Zhen Guo, Jing-Yao Guo, Bin Tan,* and Xin-Yuan xingkong星空中国官网,* "Asymmetric Synthesis of Axially Chiral Isoquinolones: Nickel-Catalyzed Denitrogenative Transannulation" Angew. Chem., Int. Ed. 2015, 54, 9528.
22. Jin-Shun Lin, Peng xingkong星空中国官网, Lin Huang, Pan Zhang, Bin Tan,* and Xin-Yuan Liu,* "Brønsted Acid-Catalyzed Asymmetric Hydroamination of Alkenes: Synthesis of Pyrrolidines Bearing a Tetrasubstituted Carbon Stereocenter" Angew. Chem., Int. Ed. 2015, 54, 7847.
21. Peng xingkong星空中国官网, Sheng-Cai Zheng, Ning-Yuan Yang, Bin Tan,* and Xin-Yuan Liu,* "Phosphine-Catalyzed Remote β-C-H Functionalization of Amine Triggered by Trifluoromethylation of Alkene: One-Pot Synthesis of Bistrifluoromethylated Enamides and Oxazoles" Angew. Chem., Int. Ed. 2015, 54, 4041.
20. Peng Yu, Jin-Shun Lin, Lei xingkong星空中国官网, Sheng-Cai Zheng, Ya-Ping Xiong, xingkong星空中国官网-Jiao Zhao, Bin Tan,* and Xin-Yuan Liu,* "Enantioselective C–H Bond Functionalization Triggered by Radical Trifluoromethylation of Unactivated Alkene" Angew. Chem., Int. Ed. 2014, 53, 11890.
19. Ji-Wei Zhang, Jin-Hui Xu, Dao-Juan Cheng, Chuan Shi, Xin-Yuan xingkong星空中国官网,* and Bin Tan,* "Discovery and Enantiocontrol of Axially Chiral Urazoles via Organocatalytic Tyrosine Click Reaction" Nat. Commun. 2016, 7, 10677.
18. Jian Zhang, Shao-Xia Lin, Dao-Juan Cheng, Xin-Yuan xingkong星空中国官网,* and Bin Tan,* "Phosphoric Acid-Catalyzed Asymmetric Classic Passerini Reaction" J. Am. Chem. Soc. 2015, 137, 14039.
17. Ye-Hui Chen, Dao-Juan Cheng, Jian Zhang, Yong Wang, Xin-Yuan xingkong星空中国官网,* Bin Tan,* "Atroposelective Synthesis of Axially Chiral Biaryldiols via Organocatalytic Arylation of 2 Naphthols" J. Am. Chem. Soc. 2015, 137, 15062.
16. Ming-Yue Wu, Wei-Wei He, Xin-Yuan xingkong星空中国官网,* and Bin Tan,* "Asymmetric Construction of Spirooxindoles via Organocatalytic Multicomponent Reactions of Diazooxindoles" Angew. Chem., Int. Ed. 2015, 54, 9409.
15. Dao-Juan Cheng, Liang Yan, Shi-Kai Tian,* Ming-Yue Wu, Lu-Xin Wang, Zi-xingkong星空中国官网 Fan, Sheng-Cai Zheng, Xin-Yuan Liu,* and Bin Tan,* "Highly Enantioselective Kinetic Resolution of Axially Chiral BINAM Derivatives Catalyzed by a Brønsted Acid" Angew. Chem., Int. Ed. 2014, 53, 3684.
14. Lin Huang, Jin-Shun Lin, Bin Tan,* Xin-Yuan xingkong星空中国官网,* "Alkene Trifluoromethylation-Initiated Remote α-Azidation of Carbonyl Compounds toward Trifluoromethyl γ-Lactam and Spirobenzofuranone-lactam" ACS Catal. 2015, 5, 2826.
13. Lin Huang, Sheng-Cai Zheng, Bin Tan,* Xin-Yuan xingkong星空中国官网,* "Metal-Free Direct 1,6- and 1,2-Difunctionalization Triggered by Radical Trifluoromethylation of Alkenes" Org. Lett. 2015, 17, 1589.
12. Lin Huang, Sheng-Cai Zheng, Bin Tan,* Xin-Yuan xingkong星空中国官网,* "Trifluoromethylation-Initiated Remote Cross-Coupling of Carbonyl Compounds to Form Carbon–Heteroatom/Carbon Bonds" Chem. Eur. J. 2015, 21, 6718.
11. Can-Liang Ma, Xiao-Long xingkong星空中国官网, Xiao-Long Zhu, Yong-Zhou Hu, Xiao-Wu Dong, Bin Tan,* and Xin-Yuan Liu,* "Platinum-Catalyzed Tandem Cyclization Reaction to Multiply Substituted Indolines under Microwave-Assisted Conditions" Adv. Synth. Catal. 2015, 357, 569.
10. Lei xingkong星空中国官网, Jing-Yao Guo, Xing-Guo Liu, Su Chen, Yong Wang, Bin Tan,* and Xin-Yuan Liu,* "Amide Groups Switch Selectivity: C–H Trifluoromethylation of α,β-Unsaturated Amides and Subsequent Asymmetric Transformation" Org. Lett., 2014, 16, 6032.
9. Jin-Shun Lin, Xiang-Geng xingkong星空中国官网, Xiao-Long Zhu, Bin Tan,* and Xin-Yuan xingkong星空中国官网,* “Copper-Catalyzed Aminotrifluoromethylation of Unactivated Alkenes with TMSCF3: Construction of Trifluoromethylated Azaheterocycles" J. Org. Chem. 2014, 79, 7084.
8. Xing-xingkong星空中国官网 Zhu, Jin-Hui Xu, Dao-Juan Cheng, xingkong星空中国官网-Jiao Zhao, Xin-Yuan Liu,* and Bin Tan,* "In Situ Generation of Electrophilic Trifluoromethylthio Reagents for Enantioselective Trifluoromethylthiolation of Oxindoles" Org. Lett. 2014, 16, 2192.
7. Ya-Ping Xiong, Ming-Yue Wu, Xiang-Yu Zhang, Can-Liang Ma, Lin Huang, xingkong星空中国官网-Jiao Zhao, Bin Tan,* and Xin-Yuan Liu,* "Direct Access to α-CF3-enones via Efficient Copper-Catalyzed Trifluoromethylation of Meyer-Schuster Rearrangement" Org. Lett. 2014, 16, 1000.
6. Lei xingkong星空中国官网, Min Deng, Sheng-Cai Zheng, Ya-Ping Xiong, Bin Tan,* and Xin-Yuan Liu,* "Metal-Free Direct Intramolecular Carbotrifluoromethylation of Alkenes to Functionalized Trifluoromethyl Azaheterocycles." Org. Lett. 2014, 16, 504.
5. Jin-Shun Lin, Ya-Ping Xiong, Can-Liang Ma, xingkong星空中国官网-Jiao Zhao, Bin Tan,* and Xin-Yuan Liu,* "Efficient Copper-Catalyzed Direct Intramolecular Aminotrifluoromethylation of Unactivated Alkenes with Diverse Nitrogen-Based Nucleophiles." Chem. Eur. J. 2014, 20, 1332.
4. Tao Liu, Da-Qiang xingkong星空中国官网, Si-Yu Wang Yong-Zhou Hu, Xiao-Wu Dong,* Xin-Yuan Liu,* and Chi-Ming Che, "Straightforward Installation of Carbon-Halogen, Carbon-Oxygen and Carbon-Carbon Bonds within Metal–Organic Frameworks via Direct C–H Functionalization." Chem. Commun. 2014, 50, 13261.
3. Tao xingkong星空中国官网, Jin-Xin Che, Yong-Zhou Hu, Xiao-Wu Dong,* Xin-Yuan xingkong星空中国官网,* and Chi-Ming Che "Alkenyl/thiol-derived Metal–Organic Frameworks via Post-Synthetic Modification for Effective Mercury Adsorption." Chem. Eur. J. 2014, 20, 14090.
2. Xiao-Wu Dong, Tao xingkong星空中国官网, Yong-Zhou Hu,* Xin-Yuan xingkong星空中国官网,* and Chi-Ming Che "Urea Postmodified in Metal-Organic Framework as Catalytically Active Hydrogen-Bond-Donating Heterogeneous Catalyst." Chem. Commun. 2013, 49, 7681.
1. Gaosheng Yang,* Chongrong Luo, Xiaolong Mu, Tingting Wang, and Xin-Yuan xingkong星空中国官网,* "Highly efficient enantioselective three-component synthesis of 2-amino-4H-chromenes catalysed by chiral tertiary amine-thioureas." Chem. Commun. 2012, 48, 5880.